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The dithiol mechanism was too slow to compete with the monothiol mechanism in the presence of GSH or GSSG and was only detected for the oxidation of roGFP2 using diamide-treated PfGrx without GSH

10.1016/s0140-6736(99)04137-9 216 SchuppP.SteubeK.MeyerC.ProkschP

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Rather than acting as an antioxidant itself, sulforaphane activates a cellular pathway known as Nrf2, which helps regulate the body's own antioxidant and detoxification systems.7 This mechanism has attracted growing interest among longevity researchers because it encourages the body to produce more of its own protective enzymes rather than simply supplying additional antioxidant compounds

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